碱金属的半径很大，而电荷仅有+1，所以碱金属通常不和简单的路易斯碱生成配合物。半径最小的Li+有最多的配合物，随着离子半径增大，形成的配合物越来越少。水溶液中，碱金属离子以八面体的六水合离子（[M(H2O)6]+）存在；由于锂离子半径小，因而形成的是正四面体的四水合离子[Li(H2O)4]+.由于水分子的极性…
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